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        <gco:CharacterString>The water chemistry data described here are from discrete water samples collected by the NOAA Coral Reef Ecosystem Program (CREP), to assess the seawater carbonate systems at fixed climate survey sites located in coral reef habitats in the Philippines in 2012, 2013, and 2015. Climate sites were established by CREP to assess multiple features of the coral reef environment (in addition to the data described herein) over time. In 2015, conductivity-temperature-depth (CTD) casts were also performed to characterize the spatial structure of the physical and chemical properties of the ocean environment influencing the living coral reef resources.   These water chemistry and CTD data provide a baseline for tracking reef carbonate system changes due to globally increasing levels of atmospheric carbon dioxide. The data can be accessed online via the NOAA National Centers for Environmental Information (NCEI) Ocean Archive.

To survey water chemistry, SCUBA divers collected two discrete water samples from each site; one at the reef and one at the surface directly above the reef. The samples were processed by CREP and sent to NOAA Pacific Marine Environmental Laboratory (PMEL) to be analyzed for total alkalinity (TA) and dissolved inorganic carbon (DIC). From these constituents, alongside temperature, salinity, and depth data, other parameters of the seawater carbonate system can be calculated. 

CTD data are collected by lowering the CTD in a profiling mode from a small boat, resulting in vertical profiles (max 18 meter depth, downcast only) of water column conductivity, temperature, and pressure. Vertical profiles of temperature, salinity, and turbidity resulting from CTD casts provide indicators for local seawater chemistry changes. 

In addition to these discrete samples, water samples were collected as part of CREP's ocean acidification diurnal suite, which also includes vertical profiles from CTD casts, current direction and magnitude from an Acoustic Doppler Current Profiler, and pH from an SeaFET sensor. The data associated with the diurnal suite are documented and archived separately;  The data associated with the diurnal suite is documented and archived separately with metadata available at https://www.fisheries.noaa.gov/inport/item/45954.</gco:CharacterString>
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        <gco:CharacterString>Laboratory experiments reveal calcification rates of crustose coralline algae (CCA) are strongly correlated to seawater aragonite saturation state. Predictions of reduced coral calcification rates, due to ocean acidification, suggest that coral reef communities will undergo ecological phase shifts as calcifying organisms are negatively impacted by changing seawater chemistry.</gco:CharacterString>
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        <gco:CharacterString>PIFSC Ecosystem Sciences Division and funded by the NOAA Coral Reef Conservation Program and the United States Agency for International Development</gco:CharacterString>
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            <gco:CharacterString>Updated and revised in October 2021 due to errors in salinity used to calculate Total Alkalinity, Dissolved Organic Carbon, pCO2, pH, and Aragonite Saturation State in previous analysis.

Initially published CTD and carbonate chemistry data together in 2017 with accession number 0162832 (deprecated as of November 2021). CTD and water sample carbonate chemistry datasets are now under separate accessions.</gco:CharacterString>
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Please cite PIFSC Ecosystem Sciences Division (ESD) when using the data.

Suggested citation:

Ecosystem Sciences Division; Pacific Islands Fisheries Science Center (2021). Water chemistry and Conductivity-Temperature-Depth (CTD) profiles at coral reef sites in Batangas, Philippines from discrete surface and bottom water samples collected from 2012 to 2015.  NOAA's National Center for Environmental Information, https://www.fisheries.noaa.gov/inport/item/45817.</gco:CharacterString>
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To examine carbonate chemistry, discrete seawater samples were taken at fixed climate sites from 2012-2015 in the Philippines.  Shallow CTD profiles were also collected from climate survey sites in Batangas, Philippines (Mabini and Tingloy) by the PIFSC Ecosystem Sciences Division in 2015 to measure conductivity, temperature, pressure, depth, salinity, and density. 

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Each header in the raw and processed files is manipulated to include the latitude, longitude, and date/time (in UTC) of the cast. The result is a standard ascii .cnv file, in addition to the raw .hex file.  THe data are then ingested into an Access database.</gco:CharacterString>
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                <gco:CharacterString>Aragonite calculations (not provided in dataset) that are of interest to CREP researchers as part of the National Coral Reef Monitoring Program are described here. 

CO2Sys is a carbonate system calculator used to calculate aragonite parameters. It can be used in programs written for Excel, Matlab, R, and many more. The source document is the CO2Sys User's Manual. The CO2Sys Excel and Matlab versions most commonly used by oceanographers can be found online at http://cdiac.ornl.gov/ftp/oceans/co2sys/. 

In section 6.3 the output variable for aragonite saturation state is "Omegas for calcite and aragonite at the output conditions"

Section 12 contains the "Omega" calculation of interest.

With all the input conditions, including temp, salinity, pressure (depth), dissolved nutrients, and 2 of the required carbonate system parameters (CREP analyzes water samples for DIC and TA) collected in the field (and included in the dataset), the rest of the carbonate values can be calculated, one of which is the omega for aragonite (i.e., aragonite saturation state).</gco:CharacterString>
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