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          <gmd:keyword>
            <gco:CharacterString>Ocean Carbon and Acidification Data System (OCADS) Project</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="project">project</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Ocean Acidification Search Keywords</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
            </gmd:CI_Citation>
          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>Canadian Arctic Archipelago</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="project">project</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Reference Section ID</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
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          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>Surface water pCO2 measurements in Hudson Bay during the spring and early-summer seasons</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="project">project</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Research Projects</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
            </gmd:CI_Citation>
          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/08fd82a1-4370-46a2-82ea-94c0f91498a7" xlink:actuate="onRequest">EARTH SCIENCE &gt; ATMOSPHERE &gt; ATMOSPHERIC PRESSURE</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/1d8525f0-0cfc-4d59-8677-da5c8038deb7" xlink:actuate="onRequest">EARTH SCIENCE &gt; CLIMATE INDICATORS &gt; ATMOSPHERIC/OCEAN INDICATORS &gt; SURFACE SALINITY</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/26afa886-4866-4536-be3a-6f9db9aacd97" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; CARBON DIOXIDE</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/46206e8c-8def-406f-9e62-da4e74633a58" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN TEMPERATURE &gt; WATER TEMPERATURE</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/7e95b5fc-1d58-431a-af36-948b29fa870d" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; SALINITY/DENSITY &gt; SALINITY</gmx:Anchor>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Science Keywords</gco:CharacterString>
              </gmd:title>
              <gmd:date>
                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2026</gco:Date>
                  </gmd:date>
                  <gmd:dateType>
                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
                  </gmd:dateType>
                </gmd:CI_Date>
              </gmd:date>
              <gmd:edition>
                <gco:CharacterString>23</gco:CharacterString>
              </gmd:edition>
              <gmd:citedResponsibleParty>
                <gmd:CI_ResponsibleParty>
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                    <gco:CharacterString>Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA)</gco:CharacterString>
                  </gmd:organisationName>
                  <gmd:contactInfo>
                    <gmd:CI_Contact>
                      <gmd:address>
                        <gmd:CI_Address>
                          <gmd:city>
                            <gco:CharacterString>Greenbelt</gco:CharacterString>
                          </gmd:city>
                          <gmd:administrativeArea>
                            <gco:CharacterString>MD</gco:CharacterString>
                          </gmd:administrativeArea>
                        </gmd:CI_Address>
                      </gmd:address>
                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
                          </gmd:linkage>
                          <gmd:protocol>
                            <gco:CharacterString>HTTPS</gco:CharacterString>
                          </gmd:protocol>
                          <gmd:name>
                            <gco:CharacterString>GCMD Keyword Forum Page</gco:CharacterString>
                          </gmd:name>
                          <gmd:description>
                            <gco:CharacterString>Global Change Master Directory (GCMD). 2025. GCMD Keywords, Version 21. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords</gco:CharacterString>
                          </gmd:description>
                          <gmd:function>
                            <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
                          </gmd:function>
                        </gmd:CI_OnlineResource>
                      </gmd:onlineResource>
                    </gmd:CI_Contact>
                  </gmd:contactInfo>
                  <gmd:role>
                    <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
                  </gmd:role>
                </gmd:CI_ResponsibleParty>
              </gmd:citedResponsibleParty>
            </gmd:CI_Citation>
          </gmd:thesaurusName>
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      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>Surface underway</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>OCADS Study Type</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
            </gmd:CI_Citation>
          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gco:CharacterString>PRES_EQU</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>PRES_LICOR</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>SSS</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>SST</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>TEMP_EQU</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>TEMP_LICOR</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>xCO2_EQU_ppm</gco:CharacterString>
          </gmd:keyword>
          <gmd:keyword>
            <gco:CharacterString>xH2O_EQU</gco:CharacterString>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Provider Variable Abbreviations</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
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          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/0bf12743-3ab8-4be7-9b48-b565723ed0ad" xlink:actuate="onRequest">BAROMETERS &gt; BAROMETERS</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/7aecabfb-0047-484f-8396-efc0da16bc20" xlink:actuate="onRequest">CO2 ANALYZERS &gt; CO2 ANALYZERS</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/d8efbcb9-9ab3-4016-b7ff-6426cd0bf545" xlink:actuate="onRequest">EQUILIBRATORS</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/ed79ec7b-a2df-4948-9877-b75e1fcb8782" xlink:actuate="onRequest">SALINOMETERS</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/aa953a14-4581-47f8-a5b3-c8dd50904ee0" xlink:actuate="onRequest">TEMPERATURE SENSORS &gt; TEMPERATURE SENSORS</gmx:Anchor>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="instrument">instrument</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Instrument Keywords</gco:CharacterString>
              </gmd:title>
              <gmd:date>
                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2026</gco:Date>
                  </gmd:date>
                  <gmd:dateType>
                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
                  </gmd:dateType>
                </gmd:CI_Date>
              </gmd:date>
              <gmd:edition>
                <gco:CharacterString>23</gco:CharacterString>
              </gmd:edition>
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                <gmd:CI_ResponsibleParty>
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                  <gmd:contactInfo>
                    <gmd:CI_Contact>
                      <gmd:address>
                        <gmd:CI_Address>
                          <gmd:city>
                            <gco:CharacterString>Greenbelt</gco:CharacterString>
                          </gmd:city>
                          <gmd:administrativeArea>
                            <gco:CharacterString>MD</gco:CharacterString>
                          </gmd:administrativeArea>
                        </gmd:CI_Address>
                      </gmd:address>
                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
                          </gmd:linkage>
                          <gmd:protocol>
                            <gco:CharacterString>HTTPS</gco:CharacterString>
                          </gmd:protocol>
                          <gmd:name>
                            <gco:CharacterString>GCMD Keyword Forum Page</gco:CharacterString>
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                            <gco:CharacterString>Global Change Master Directory (GCMD). 2025. GCMD Keywords, Version 21. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords</gco:CharacterString>
                          </gmd:description>
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                            <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                        </gmd:CI_OnlineResource>
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                    </gmd:CI_Contact>
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                    <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
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      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/1bb21d0f-bf48-42b5-8e09-cc0d58407e4a" xlink:actuate="onRequest">Ships</gmx:Anchor>
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          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="platform">platform</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Platform Keywords</gco:CharacterString>
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              <gmd:date>
                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2026</gco:Date>
                  </gmd:date>
                  <gmd:dateType>
                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
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                <gco:CharacterString>23</gco:CharacterString>
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                            <gco:CharacterString>Greenbelt</gco:CharacterString>
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                          <gmd:administrativeArea>
                            <gco:CharacterString>MD</gco:CharacterString>
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                      </gmd:address>
                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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                            <gco:CharacterString>HTTPS</gco:CharacterString>
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                    <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
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      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://vocab.ices.dk/services/pox/GetCodeDetail/SHIPC/18DL" xlink:actuate="onRequest">Amundsen (call sign: CGDT, ICES code: 18DL, 2003-)</gmx:Anchor>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="platform">platform</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>ICES/SeaDataNet Ship Codes</gco:CharacterString>
              </gmd:title>
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          </gmd:thesaurusName>
        </gmd:MD_Keywords>
      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/1ed45273-3e2b-4586-b852-05578c04041b" xlink:actuate="onRequest">OCEAN &gt; ARCTIC OCEAN</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/a4202721-0cba-4fa1-853f-890f146b04f9" xlink:actuate="onRequest">OCEAN &gt; ATLANTIC OCEAN &gt; NORTH ATLANTIC OCEAN</gmx:Anchor>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="place">place</gmd:MD_KeywordTypeCode>
          </gmd:type>
          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>Global Change Master Directory (GCMD) Location Keywords</gco:CharacterString>
              </gmd:title>
              <gmd:date>
                <gmd:CI_Date>
                  <gmd:date>
                    <gco:Date>2026</gco:Date>
                  </gmd:date>
                  <gmd:dateType>
                    <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="revision">revision</gmd:CI_DateTypeCode>
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                </gmd:CI_Date>
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                <gco:CharacterString>23</gco:CharacterString>
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              <gmd:citedResponsibleParty>
                <gmd:CI_ResponsibleParty>
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                  <gmd:contactInfo>
                    <gmd:CI_Contact>
                      <gmd:address>
                        <gmd:CI_Address>
                          <gmd:city>
                            <gco:CharacterString>Greenbelt</gco:CharacterString>
                          </gmd:city>
                          <gmd:administrativeArea>
                            <gco:CharacterString>MD</gco:CharacterString>
                          </gmd:administrativeArea>
                        </gmd:CI_Address>
                      </gmd:address>
                      <gmd:onlineResource>
                        <gmd:CI_OnlineResource>
                          <gmd:linkage>
                            <gmd:URL>https://forum.earthdata.nasa.gov/app.php/tag/GCMD%2BKeywords</gmd:URL>
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                            <gco:CharacterString>HTTPS</gco:CharacterString>
                          </gmd:protocol>
                          <gmd:name>
                            <gco:CharacterString>GCMD Keyword Forum Page</gco:CharacterString>
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                <gmd:CI_ResponsibleParty>
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                    <gco:CharacterString>Navigate directly to the URL for a descriptive web page with download links.</gco:CharacterString>
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                            <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="publication">publication</gmd:CI_DateTypeCode>
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                          <gmd:contactInfo>
                            <gmd:CI_Contact>
                              <gmd:onlineResource>
                                <gmd:CI_OnlineResource>
                                  <gmd:linkage>
                                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/0246726/1.1</gmd:URL>
                                  </gmd:linkage>
                                  <gmd:protocol>
                                    <gco:CharacterString>HTTPS</gco:CharacterString>
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                                    <gco:CharacterString>NCEI Accession 0246726 v1.1</gco:CharacterString>
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                                  <gmd:description>
                                    <gco:CharacterString>published 2022-01-28T23:07:11Z</gco:CharacterString>
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                    </gmd:CI_Citation>
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                </gmi:LE_Source>
              </gmi:output>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:dataQualityInfo>
    <gmd:DQ_DataQuality>
      <gmd:scope>
        <gmd:DQ_Scope>
          <gmd:level>
            <gmd:MD_ScopeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="dataset">dataset</gmd:MD_ScopeCode>
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        </gmd:DQ_Scope>
      </gmd:scope>
      <gmd:lineage>
        <gmd:LI_Lineage>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pCO2 (fCO2) autonomous;
Abbreviation: xCO2_EQU_ppm;
Unit: micromol per mol (or ppm);
Observation type: surface underway;
Measured or calculated: measured;
Sampling instrument: GO 8050 underway pCO2 system;
Location of seawater intake: engine room of CCGS Amundsen;
Analyzing instrument: non-dispersive Infrared gas analyzer;
Detailed sampling and analyzing information: See Pierrot et al. [2009] for more details on GO 8050 underway system. pCO2 is calculated from the CO2 molar fraction, the equilibrator pressure, and the water vapour pressure (estimated from surface water salinity and temperature using Weiss and Price [1980]) following Dickson et al. [2007]. Then a temperature correction was applied to account for warming of seawater from the seawater intake to the GO8050 equilibrator. A temperature sensor was installed directly at the seawater intake to measure in-situ SST directly, and we used these values to temperature-correct our pCO2 values using the formula from Takahashi et al. (1993);
Equilibrator type: shower-type equilibrator;
Is the equilibrator vented or not: vented;
Water flow rate: 2.4-2.8 L/min;
Gas flow rate: ~100 ml/min;
How was temperature inside the equilibrator measured: Temperature inside the equilibarator measured with a very accurate (±0.01 °C) and stable Hart digital thermometer with a thermistor probe. However, we applied a temperature correction to account for warming from the seawater intake line to the GO 8050 equilibrator. The temperature correction was done with a regression analysis between the equilibrator water temperature and it's coincident seawater measurements made by the ship's CTD-rosette. The computed SST values from this linear relationship are the temperatures at which our pCO2 values are reported. Details about this regression, and the statistics of it are included in the second tab of this spreadsheet.;
How was pressure inside the equilibrator measured: Setra pressure transducer, differential measurement;
Drying method for gas: headspace gas from the equilibrator goes through a condensor, then Naphion drying tubes, then to the CO2 analyzer;
SEA CO2 gas detector manufacturer: LICOR;
SEA CO2 gas detector model: LI-7000;
SEA CO2 gas detector resolution: the precision of the measurements is ± 1 ppm (see Pierrot et al. 2009) the accuracy of the instrument is nominal ± 1% (see Pierrot et al. 2009);
Standardization technique: The LI-7000 is calibrated with a zero CO2 gas (ultra-pure N2 gas from Praxair), and three span gases (254.5, 431.3, and 554.2 ppm from Praxair), twice daily. These are secondary standards, which are calibrated using primary standards from NOAA.;
Standardization frequency: twice daily;
Standard gas manufacturer: Praxair;
Standard gas concentration: zero CO2 gas (ultra-pure N2 gas from Praxair), and three span gases (at concentrations of 295.8, 448.6, and 551.7 ppm from Praxair);
Standard gas uncertainty: since the concentrations of standard gases are measured using the LI-7000 after a calibration with NOAA standards, the uncertainty of the standard gas CO2 concentrations should be +/- 1 ppm;
Water vapor correction method: Weiss and Price [1980];
Temperature correction method: Takahashi et al. [1993];
At what temperature was pCO2 reported: pCO2 is reported at SST temperatures (measured by a temperature sensor located directly at the seawater intake);
Uncertainty: Uncertainty of +/- 2 ppm (Pierrot et al., 2009);
Method reference: Pierrot, D., Neill, C., Sullivan, K., Castle, R., Wanninkhof, R., Lüger, H., Johannessen, T., Olsen, A., Feely, R. A., &amp; Cosca, C. E. (2009). Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines. Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522. https://doi.org/10.1016/j.dsr2.2008.12.005;
Researcher name: Mohamed Ahmed;
Researcher institution: University of Calgary</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: H2O molar fraction;
Abbreviation: xH2O_EQU;
Unit: millimol per mol (or ppt);
Observation type: surface underway;
Sampling instrument: GO 8050 underway pCO2 system;
Analyzing instrument: LI-7000;
Uncertainty: The precision of the measurements is 0.05 ppt, and the accuracy of the instrument is 1%</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: temperature of gas analyzer;
Abbreviation: TEMP_LICOR;
Unit: degrees celcius;
Observation type: surface underway;
Sampling instrument: GO 8050 underway pCO2 system;
Analyzing instrument: temperature sensor inside the LI-7000 is the Betatherm model 100K6MBD1;
Uncertainty: accuracy better than 0.05 deg C</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pressure of gas analyzer;
Abbreviation: PRES_LICOR;
Unit: hPa;
Observation type: surface underway;
Sampling instrument: GO 8050 underway pCO2 system;
Analyzing instrument: pressure sensor inside LI-7000 is the 13A-015A pressure sensor.;
Uncertainty: accuracy of 0.1%</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pressure inside equilibrator;
Abbreviation: PRES_EQU;
Unit: hPa;
Observation type: surface underway;
Sampling instrument: GO 8050 underway pCO2 system;
Analyzing instrument: Setra pressure transducer, differential measurement;
Uncertainty: accuracy of +/- 0.027 hPa;
Method reference: calculated PRES_EQU by adding differential pressure measurement from Setra pressure transducer to PRES_LICOR (ambient pressure)</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: temperature of water inside equilibrator;
Abbreviation: TEMP_EQU;
Unit: degrees celcius;
Observation type: surface underway;
Sampling instrument: GO 8050 underway pCO2 system;
Analyzing instrument: Hart thermometer;
Uncertainty: accuracy of +/- 0.025 deg C</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: sea surface temperature;
Abbreviation: SST;
Unit: degrees celcius;
Observation type: surface underway;
Analyzing instrument: Omega type T thermocouple;
Uncertainty: 0.5 deg C standard limit of error, for more information (ANSI code T): https://www.omega.ca/techref/colorcodes.html</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: sea surface salinity;
Abbreviation: SSS;
Unit: practical salinity units;
Observation type: surface underway;
Sampling instrument: GO 8050 underway pCO2 system;
Analyzing instrument: Idronaut Ocean Seven model 315;
Uncertainty: accuracy of 0.003 mS/cm in conductivity measurement</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
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  </gmd:dataQualityInfo>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be21">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>barometric pressure sensor</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>barometric pressure sensor</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>instrument used to measure the atmospheric pressure.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be58">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
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        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bea4">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>salinometer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>salinometer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>generic salinometer

use salinometer when the instrument type used is unclear but the data include salinity measurements</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be57">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>extracts dissolved CO2 from water

A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside.

Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be41">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>temperature sensor</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>temperature sensor</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>A sensor used to measure temperature.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:platform>
        <gmi:MI_Platform id="plat_902b">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>CCGS Amundsen</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:description>
            <gco:CharacterString>ICES request for the vessel Amundsen from CANADA.
NOTE: Canada platform SIR JOHN FRANKLIN (NODC Code=18SZ) is a previous name for this platform and had the same call sign.

Name : Amundsen
Flag : CANADA - CA (ISO Country Code)
Call Sign : CGDT
Title : CCGS
Platform Class : 31 Research vessel
IMO : 7510846
Commissioned Date : 2003
Current Length : 98.33
Built : 1979
Previous Name (Notes): SIR JOHN FRANKLIN
Notes : Converted to coast guard icebreaker/research vessel in 2003

Additional Information Sources:

- http://www.amundsen.ulaval.ca/index.php?url=11210

Same Vessels Info:
18SZ - SIR JOHN FRANKLIN

Confirmed by NOAA on 2013-04-15.</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
      </gmi:platform>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>