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                <gco:CharacterString>NODC COLLECTING INSTITUTION NAMES THESAURUS</gco:CharacterString>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="dataCentre">dataCentre</gmd:MD_KeywordTypeCode>
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            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>NODC SUBMITTING INSTITUTION NAMES THESAURUS</gco:CharacterString>
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      <gmd:descriptiveKeywords>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/project/details/658" xlink:actuate="onRequest">Surface Ocean CO2 Atlas (SOCAT)</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/project/details/675" xlink:actuate="onRequest">US DOC; NOAA; Office of Oceanic and Atmospheric Research; Ocean Acidification Program (OAP)</gmx:Anchor>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="project">project</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>NODC PROJECT NAMES THESAURUS</gco:CharacterString>
              </gmd:title>
              <gmd:date gco:nilReason="inapplicable" />
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      <gmd:descriptiveKeywords>
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            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/seaname/details/15" xlink:actuate="onRequest">Gulf of Alaska</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/seaname/details/93" xlink:actuate="onRequest">North Pacific Ocean</gmx:Anchor>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="place">place</gmd:MD_KeywordTypeCode>
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              <gmd:title>
                <gco:CharacterString>NODC SEA AREA NAMES THESAURUS</gco:CharacterString>
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            <gco:CharacterString>oceanography</gco:CharacterString>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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                <gco:CharacterString>WMO_CategoryCode</gco:CharacterString>
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          <gmd:thesaurusName>
            <gmd:CI_Citation>
              <gmd:title>
                <gco:CharacterString>EXPOCODE</gco:CharacterString>
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                <gco:CharacterString>Ocean Acidification Search Keywords</gco:CharacterString>
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            <gco:CharacterString>Coastal</gco:CharacterString>
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                <gco:CharacterString>Reference Section ID</gco:CharacterString>
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      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
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            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/a65cfcfa-1028-4cc8-a4d5-9e78f487a612" xlink:actuate="onRequest">EARTH SCIENCE &gt; ATMOSPHERE &gt; ATMOSPHERIC CHEMISTRY &gt; CARBON AND HYDROCARBON COMPOUNDS &gt; ATMOSPHERIC CARBON DIOXIDE &gt; PARTIAL PRESSURE OF CARBON DIOXIDE</gmx:Anchor>
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            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/46206e8c-8def-406f-9e62-da4e74633a58" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN TEMPERATURE &gt; WATER TEMPERATURE</gmx:Anchor>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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                            <gco:CharacterString>HTTPS</gco:CharacterString>
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                            <gco:CharacterString>Global Change Master Directory (GCMD). 2025. GCMD Keywords, Version 21. Greenbelt, MD: Earth Science Data and Information System, Earth Science Projects Division, Goddard Space Flight Center (GSFC), National Aeronautics and Space Administration (NASA). URL (GCMD Keyword Forum Page): https://forum.earthdata.nasa.gov/app.php/tag/GCMD+Keywords</gco:CharacterString>
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                <gco:CharacterString>OCADS Study Type</gco:CharacterString>
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            <gco:CharacterString>seawater pCO2</gco:CharacterString>
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              <gmd:title>
                <gco:CharacterString>Provider Variable Abbreviations</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: pCO2 (fCO2) autonomous;
Abbreviation: seawater pCO2;
Unit: µatm;
Observation type: Measurements from continuously flowing seawater stream;
Measured or calculated: Measured;
Calculation method and parameters: Calculated from measured CO2 mole fractions (xCO2) and ambient atmospheric pressure;
Sampling instrument: equilibrator;
Location of seawater intake: Seawater drawn from 4.3-m (14 feet) depth to the OceansAlaska Shellfish Hatchery barge in Ketchikan; southeast Alaska; 55.3150°N, 131.5954°W;
Depth of seawater intake: 4.3-m;
Analyzing instrument: Dakunalytics, LLC Burke-o-Lator (BoL) pCO2/TCO2 analyzer with LI-COR LI-840A;
Detailed sampling and analyzing information: Seawater pCO2 data were calculated from corrected measurements of CO2 mixing ratio (xCO2) made using a Dakunalytics, LLC Burke-o-Lator pCO2/TCO2 analyzer following many recommended protocols by Pierrot et al. (2009) with the system theory and calculations described in detail elsewhere (Hales et al., 2004). Seawater continuously flowed between 0.5 and 1 gpm first through a Sea-Bird SBE45 thermosalinograph and into a bubble-type equilibrator. Seawater supplied to the equilibrator enters the top of the equilibration chamber through a vertical tube before contacting a dispersion plate that diverts seawater radically. Carrier gas (marine air) is pumped into the bubble-type equilibrator from the BoL electronics box at ~200 ml min-1 and enters the equilibration chamber through drip garden hose tubing positioned around the seawater dispersion plate in order to maximize the bubble production and subsequent equilibration of the carrier gas in the chamber. Full equilibration was verified by injecting high and low CO2 gas standard into the equilibration chamber and verifying carrier gas concentrations returned to the same pre-disturbance xCO2. These tests also revealed the response time of the equilibrator to be ~5 mins. Equilibrated carrier gas is then supplied to a non-dispersive infrared gas analyzer (LI-COR LI840A CO2/H2O) housed within the BoL electronics box. Carrier gas is then recirculated through the system, minimizing the need for make-up by the equilibrator. Pressure and temperature were continuously measured in the equilibrator using an Omega Pressure Sensor and Fast Response Resistance Temperature Detector (RTD), respectively. The RTD periodically stopped reporting data, so the thermosalinograph temperature is taken here to equal equilibrator temperature as these components were adjacent to each other and there was very close agreement between the RTD and the thermosalinograph. Equilibrated carrier gas, four standard gases of known mixing ratio (149.3, 451, and 752 ppm; Scott-Marin, Inc.), and unaltered marine air were all plumbed to provide gas flow to the BoL electronics box. The BoL is controlled using National Instruments LabVIEW software run on an iMac computer. The software controls data acquisition from the thermosalinograph, the pressure and temperature sensors, and the LI-COR; while also controlling Valco Instruments Co. Inc. (VICI) multi-port actuators that cycle between the gas streams plumbed to the electronics box. None of the gas streams were dried prior to analysis, and all measurements were made at 1 Hz. The prescribed measurement scheme controlled by the software was to supply equilibrated carrier gas from the equilibrator to the LI-COR continuously for 720 minutes, then cycle the actuators to consecutively allow the four standard gas streams and unaltered marine air to be measured for 90 s at 100 ml min-1 before returning to sample the carrier gas equilibrated with seawater xCO2. From each sequence of standard gas measurements, the final 20 s of data in the 50 s interval before the actuator changed position were used to construct calibration functions that were then interpolated in time between standard gas sequences. These functions were then used to calibrate the xCO2 measurements of seawater equilibrated carrier gas. Corrected seawater xCO2 was subsequently adjusted for under-pressurization in the equilibrator using the ratio of equilibrator to vented LI-COR cell pressure, and then converted to pCO2 using atmospheric pressure measured by the LI-COR. The 1 Hz seawater pCO2, temperature and salinity data were quality controlled, and then bin-averaged in 5-min interval bins. pCO2 at the equilibrator temperature was adjusted to sea surface temperature using the mean observed temperature difference between the Sea-Bird SBE45 thermosalinograph and a SAMI-Alk system deployed for a 3-week period (April 5-30, 2019) at the seawater intake.;
Equilibrator type: non-dispersive infrared gas analyzer;
Standardization technique: xCO2 calibration functions developed during periodic sequential analysis of gas standards of known concentration (149.3, 451, and 752 ppm; Praxair);
Standardization frequency: Every 720 minutes;
Standard gas manufacturer: Praxair, Inc.;
Standard gas uncertainty: 2 ppm for calibrated xCO2; ~2 µatm for pCO2;
Uncertainty: 2 µatm;
Quality flag convention: no quality flag applied;
Method reference: Hales, B., D. Chipman, and T. Takahashi (2004), High-frequency measurements of partial pressure and total concentration of carbon dioxide in seawater using microporous hydrophobic membrane contactors, Limnology and Oceanography: Methods, 2, 356-364; Pierrot, D., C. Neill, K. Sullivan, R. Castle, R. Wanninkhof, H. Lüger, T. Johannessen, A. Olsen, R. A. Feely, and C. E. Cosca (2009), Recommendations for autonomous underway pCO2 measuring systems and data-reduction routines, Deep Sea Research Part II: Topical Studies in Oceanography, 56(8-10), 512-522, https://doi.org/10.1016/j.dsr2.2008.12.005; Evans, W., Pocock, K., Hare, A., Weekes, C., Hales, B., Jackson, J., Gurney-Smith, H., Mathis, J.T., Alin, S.R., and Feely, R.A. 2019. Marine CO2 Patterns in the Northern Salish Sea. Frontiers in Marine Science 5(536): https://doi.org/10.3389/fmars.2018.00536.;
Researcher name: Wiley Evans;
Researcher institution: Hakai Institute</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Sea surface temperature;
Abbreviation: SST;
Unit: °C, ITS-90 scale;
Observation type: Measurements from continuously flowing seawater stream;
Analyzing instrument: Sea-Bird SBE 45 MicroTSG Thermosalinograph;
Detailed sampling and analyzing information: 1 Hz data captured using National Instruments LabVIEW software on an iMac computer;
Uncertainty: 0.002°C;
Researcher name: Wiley Evans;
Researcher institution: Hakai Institute</gco:CharacterString>
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Abbreviation: Salinity;
Unit: 1978 Practical Salinity Scale;
Observation type: measurements from continuously flowing seawater stream;
Calculation method and parameters: calculated from conductivity and temperature measurements;
Analyzing instrument: SBE 45 MicroTSG Thermosalinograph;
Detailed sampling and analyzing information: 1 Hz data captured using National Instruments LabVIEW software on an iMac computer;
Uncertainty: 0.003 S/m;
Researcher name: Wiley Evans;
Researcher institution: Hakai Institute</gco:CharacterString>
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Developed by Pacific Marine Environmental Laboratory and Monterey Bay Aquarium Research Institute, the h-shaped bubble equilibrator does not require a water pump to spray water from the top.

see Takahashi 1961 for more information.</gco:CharacterString>
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Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
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use salinometer when the instrument type used is unclear but the data include salinity measurements</gco:CharacterString>
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