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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/307" xlink:actuate="onRequest">SALINITY</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/5" xlink:actuate="onRequest">total alkalinity</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/datatype/details/373" xlink:actuate="onRequest">WATER TEMPERATURE</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/insttype/details/8" xlink:actuate="onRequest">CTD</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/insttype/details/210" xlink:actuate="onRequest">Niskin bottle</gmx:Anchor>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/insttype/details/199" xlink:actuate="onRequest">titrator</gmx:Anchor>
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      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/obstype/details/3" xlink:actuate="onRequest">chemical</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/obstype/details/52" xlink:actuate="onRequest">discrete sample</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/obstype/details/14" xlink:actuate="onRequest">physical</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/obstype/details/18" xlink:actuate="onRequest">profile</gmx:Anchor>
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          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="theme">theme</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
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                <gco:CharacterString>NODC OBSERVATION TYPES THESAURUS</gco:CharacterString>
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      </gmd:descriptiveKeywords>
      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/104" xlink:actuate="onRequest">Bedford Institute of Oceanography</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/962" xlink:actuate="onRequest">Department of Fisheries and Oceans Canada</gmx:Anchor>
          </gmd:keyword>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/1793" xlink:actuate="onRequest">Gulf Fisheries Centre</gmx:Anchor>
          </gmd:keyword>
          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="dataCentre">dataCentre</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
            <gmd:CI_Citation>
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                <gco:CharacterString>NODC COLLECTING INSTITUTION NAMES THESAURUS</gco:CharacterString>
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      <gmd:descriptiveKeywords>
        <gmd:MD_Keywords>
          <gmd:keyword>
            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/institution/details/962" xlink:actuate="onRequest">Department of Fisheries and Oceans Canada</gmx:Anchor>
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          <gmd:type>
            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="dataCentre">dataCentre</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
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              <gmd:title>
                <gco:CharacterString>NODC SUBMITTING INSTITUTION NAMES THESAURUS</gco:CharacterString>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="project">project</gmd:MD_KeywordTypeCode>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="place">place</gmd:MD_KeywordTypeCode>
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          <gmd:thesaurusName>
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                <gco:CharacterString>NODC SEA AREA NAMES THESAURUS</gco:CharacterString>
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                <gco:CharacterString>WMO_CategoryCode</gco:CharacterString>
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                <gco:CharacterString>Global Change Master Directory (GCMD) Data Center Keywords</gco:CharacterString>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="project">project</gmd:MD_KeywordTypeCode>
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              <gmd:title>
                <gco:CharacterString>Ocean Acidification Search Keywords</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Dissolved Inorganic Carbon;
Abbreviation: TCARBN;
Unit: umol / kg;
Observation type: discrete;
Measured or calculated: measured;
Sampling instrument: CTD and rosette bottle sampler: Niskin bottle; 5 L;
Analyzing instrument: SOMMA with UIC 5011 coulometer;
Detailed sampling and analyzing information: Seawater samples were collected from standard depths in 500 mL borosilicate glass reagent bottles. Five mL of water was removed to allow room for thermal expansion and the sample was preserved within 30 minutes of collection with 0.1 mL of a mercuric chloride saturated solution; then sealed with Apiezon M grease and the ground glass stoppers secured in place with rubber bands. The samples were stored at room temperature until on-shore laboratory analysis. The samples were analysed for DIC using a SOMMA sample handling system in conjunction with a coulometer (UIC Inc.) to quantify total CO2 purged from the acidified sample. Measurements of a Certified reference material seawater (CRMs; Scripps Oceanographic Institution) were used for calibrating DIC with each batch of 20 samples being bracketed by duplicate CRM measurements.;
Replicate information: Referenced to duplicate measurement of CRM prior to; and following; each daily batch of DIC samples;
Standardization description: Referenced to duplicate measurement of CRM prior to; and following; each daily batch of DIC samples;
Standardization frequency: To bracket each batch of 20 samples;
CRM manufacturer: Andrew Dickson's Lab at Scripps Institute of Oceanography (co2crms@ucsd.edu);
CRM batch number: 150;
Preservation method: Mercuric chloride saturated solution;
Preservative volume: 100 uL per 500 ml sample bottle = 0.02%;
Preservative correction: None;
Uncertainty: 0.0015 umol.kg;
Quality flag convention: 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled;
Method reference: Dickson; A.G.; Sabine; C.L. and Christian; J.R. (Eds.) 2007. Guide to Best Practices for Ocean CO2 Measurements. PICES Special Publication 3; 191 pp.; https://cdiac.ess-dive.lbl.gov/ftp/oceans/Handbook_2007/Guide_all_in_one.pdf;
Researcher name: Kumiko Azetsu-Scott;
Researcher institution: Bedford Institute of Oceanography</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: Total alkalinity;
Abbreviation: ALKALI;
Unit: umol / kg;
Observation type: discrete;
Measured or calculated: measured;
Calculation method and parameters: Concentration (umol / kg) = concentration (umoles/litre) / density (10 C;S);
Sampling instrument: CTD and rosette bottle sampler: Niskin bottle; 5 L;
Analyzing instrument: In-house automated sampler with Metrohm Titrando dosimat and Tiamo software;
Type of titration: Potentiometric multi point titration;
Cell type (open or closed): Open;
Curve fitting method: Gran point;
Detailed sampling and analyzing information: Seawater samples were collected from standard depths in 500 mL borosilicate glass reagent bottles. Five mL of water was removed to allow room for thermal expansion and the sample was preserved within 30 minutes of collection with 0.1 mL of a mercuric chloride saturated solution; then sealed with Apiezon M grease and the ground glass stoppers secured in place with rubber bands. The samples were stored at room temperature until on-shore laboratory analysis. TA in the sample was determined using an open cell automated potentiometric titration with a Metrohm Titrando dosing unit controlled by Metrohm Tiamo software. The multi-point titration; using 0.1N HCl titrant containing 35 g of sodium chloride per litre of acid; was performed in a temperature controlled flask held at 25 ¬∞C with Gran endpoint determination. Measurements of a Certified reference material seawater (CRMs; Scripps Oceanographic Institution) were used for calibrating TA with each batch of 20 samples being bracketed by duplicate CRM measurements.;
Replicate information: Monoplicate sample / monoplicate measurement;
Standardization description: Referenced to duplicate measurement of CRM prior to each daily batch of samples;
Standardization frequency: Each batch of 20 samples;
CRM manufacturer: Andrew Dickson's Lab at Scripps Institute of Oceanography;
CRM batch number: 150;
Preservation method: Mercuric chloride saturated solution;
Preservative volume: 100 uL per 500 ml sample bottle = 0.02%;
Preservative correction: none;
TA blank correction: Averages between 10-40 umol / kg;
Uncertainty: 0.0025;
Quality flag convention: 1 = Sample drawn from bottle but analysis not recieved; 2 = QC Performed: Acceptable Measurement; 3 = QC Performed: Questionable Measurement; 4 = QC Performed: Bad Measurement; 5 = QC Performed: Not Reported; 6 = Mean of replicate measurements; 7 = Manual chromatographic peak measurement; 8 = Irregular digital chromatographic peak integration; 9 = Not sampled;
Method reference: This is method described in SOP 3a of Dickson; A.G.; Sabine; C.L. and Christian; J.R. (Eds.) 2007. Guide to Best Practices for Ocean CO2 Measurements. PICES Special Publication 3; 191 pp;
Researcher name: Kumiko Azetsu-Scott;
Researcher institution: Bedford Institute of Oceanography</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: CTD Temperature;
Abbreviation: CTDTMP;
Unit: degrees celcius;
Observation type: CTD sensor;
Sampling instrument: CTD;
Analyzing instrument: CTD;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value</gco:CharacterString>
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                <gco:CharacterString>Parameter or Variable: CTD Salinity;
Abbreviation: CTDSAL;
Observation type: CTD sensor;
Sampling instrument: CTD;
Analyzing instrument: CTD;
Quality flag convention: WOCE quality control flags are used: 2 = good value, 3 = questionable value, 4 = bad value</gco:CharacterString>
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            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be58">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bee7">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>CTD</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>CTD</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>Conductivity-Temperature-Depth probe</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be3d">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>Niskin bottle</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>Niskin bottle</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>Device for obtaining samples of seawater at a specific depth

Why special entry for Niskin bottle but no entry for Nansen bottle?</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be28">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>titrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>