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                <gco:CharacterString>[accessed 2024-02-08]</gco:CharacterString>
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                  <gmd:date>
                    <gco:Date>2022</gco:Date>
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                        <gmd:CI_OnlineResource>
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                            <gco:CharacterString>HTTPS</gco:CharacterString>
                          </gmd:protocol>
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      <gmd:topicCategory>
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          <gmd:temporalElement>
            <gmd:EX_TemporalExtent id="boundingTemporalExtent">
              <gmd:extent>
                <gml:TimePeriod gml:id="boundingTemporalExtentPeriod">
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                  <gml:endPosition>2016-10-28</gml:endPosition>
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        <gmd:MD_Distributor>
          <gmd:distributorContact>
            <gmd:CI_ResponsibleParty>
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                <gmx:Anchor xlink:href="https://ror.org/04r0wrp59" xlink:actuate="onRequest">NOAA National Centers for Environmental Information</gmx:Anchor>
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                  </gmd:phone>
                  <gmd:address>
                    <gmd:CI_Address>
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            <gmd:MD_StandardOrderProcess>
              <gmd:fees>
                <gco:CharacterString>In most cases, electronic downloads of the data are free. However, fees may apply for custom orders, data certifications, copies of analog materials, and data distribution on physical media.</gco:CharacterString>
              </gmd:fees>
              <gmd:orderingInstructions>
                <gco:CharacterString>Contact NCEI for other distribution options and instructions.</gco:CharacterString>
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                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://www.ncei.noaa.gov/data/oceans/ncei/ocads/metadata/0172095.html</gmd:URL>
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                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Web browser</gco:CharacterString>
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                  <gmd:name>
                    <gco:CharacterString>Project Metadata</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for a descriptive web page with download links.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://doi.org/10.7289/v5r49p2w</gmd:URL>
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                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
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                  <gmd:applicationProfile>
                    <gco:CharacterString>Web browser</gco:CharacterString>
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                  <gmd:name>
                    <gco:CharacterString>NCEI Dataset Landing Page</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for a descriptive web page with download links.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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              </gmd:onLine>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/oas/172095</gmd:URL>
                  </gmd:linkage>
                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Web browser</gco:CharacterString>
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                  <gmd:name>
                    <gco:CharacterString>Descriptive Information</gco:CharacterString>
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                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for a descriptive web page with download links.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="information">information</gmd:CI_OnLineFunctionCode>
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                </gmd:CI_OnlineResource>
              </gmd:onLine>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/download/172095</gmd:URL>
                  </gmd:linkage>
                  <gmd:protocol>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Web browser</gco:CharacterString>
                  </gmd:applicationProfile>
                  <gmd:name>
                    <gco:CharacterString>HTTPS</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>Navigate directly to the URL for data access and direct download.</gco:CharacterString>
                  </gmd:description>
                  <gmd:function>
                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
                  </gmd:function>
                </gmd:CI_OnlineResource>
              </gmd:onLine>
              <gmd:onLine>
                <gmd:CI_OnlineResource>
                  <gmd:linkage>
                    <gmd:URL>ftp://ftp-oceans.ncei.noaa.gov/nodc/archive/arc0118/0172095/</gmd:URL>
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                  <gmd:protocol>
                    <gco:CharacterString>FTP</gco:CharacterString>
                  </gmd:protocol>
                  <gmd:applicationProfile>
                    <gco:CharacterString>Any FTP client</gco:CharacterString>
                  </gmd:applicationProfile>
                  <gmd:name>
                    <gco:CharacterString>FTP</gco:CharacterString>
                  </gmd:name>
                  <gmd:description>
                    <gco:CharacterString>These data are available through the File Transfer Protocol (FTP). FTP is no longer supported by most internet browsers. You may copy and paste the FTP link to the data into an FTP client (e.g., FileZilla or WinSCP).</gco:CharacterString>
                  </gmd:description>
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                    <gmd:CI_OnLineFunctionCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
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        </gmd:MD_Distributor>
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  </gmd:distributionInfo>
  <gmd:dataQualityInfo>
    <gmd:DQ_DataQuality>
      <gmd:scope>
        <gmd:DQ_Scope>
          <gmd:level>
            <gmd:MD_ScopeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="dataset">dataset</gmd:MD_ScopeCode>
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                <gco:CharacterString>NCEI Accession 0172095 v1.1 was published.</gco:CharacterString>
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              <gmd:dateTime>
                <gco:DateTime>2018-04-06T18:24:06Z</gco:DateTime>
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                          <gmd:date gco:nilReason="inapplicable" />
                          <gmd:dateType>
                            <gmd:CI_DateTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_DateTypeCode" codeListValue="publication">publication</gmd:CI_DateTypeCode>
                          </gmd:dateType>
                        </gmd:CI_Date>
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                        <gmd:CI_ResponsibleParty>
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                          <gmd:contactInfo>
                            <gmd:CI_Contact>
                              <gmd:onlineResource>
                                <gmd:CI_OnlineResource>
                                  <gmd:linkage>
                                    <gmd:URL>https://www.ncei.noaa.gov/archive/accession/0172095/1.1</gmd:URL>
                                  </gmd:linkage>
                                  <gmd:protocol>
                                    <gco:CharacterString>HTTPS</gco:CharacterString>
                                  </gmd:protocol>
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                                    <gco:CharacterString>NCEI Accession 0172095 v1.1</gco:CharacterString>
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                                    <gco:CharacterString>published 2018-04-06T18:24:06Z</gco:CharacterString>
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      <gmd:lineage>
        <gmd:LI_Lineage>
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            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: pCO2 (fCO2) autonomous;
Abbreviation: xCO2, fCO2;
Unit: ppm, uatm;
Observation type: Surface underway;
Measured or calculated: Measured;
Sampling instrument: Seawater pump;
Analyzing instrument: NDIR - Poisson et al., 1993, JGR;
Equilibrator type: Thin Film, Home-made equilibration cell (LOCEAN), Poisson et al., 1993, JGR;
Equilibrator volume: 2 (L/min);
Is the equilibrator vented or not: Vented: each 20 mn;
Water flow rate: 2 L/min;
Drying method for gas: Thermoelectric cooling units followed by permeable membrane dryer and magnessium perchlorate tube;
SEA CO2 gas detector manufacturer: Siemens;
SEA CO2 gas detector model: Ultramat 6F;
SEA CO2 gas detector resolution: Precision 0.5 uatm;
SEA CO2 gas detector uncertainty: Accuracy 2 uatm (include SST correction);
Standardization technique: Primary standards traceable to the WMO-X93 scale. Primary standards from NOAA calibrated in 2008;
Standard gas manufacturer: Three CO2 calibration gases used every 5h to 7h. Manufacturer: Air Liquide.;
Standard gas concentration: Pre and post-cruise Certified measurements at LSCE/IPSL : 279.31 ppm, 350.71 ppm, 489.94 ppm (Last certification, Jul-2017);
At what temperature was pCO2 reported: In situ sea surface temperature;
Quality flag convention: 2 = good; 3 = questionable; 4 = bad; 9 = missing data.;
Method reference: Poisson et al., 1993, JGR;
Researcher name: Claire Lo Monaco;
Researcher institution: Univ P et M Curie, France</gco:CharacterString>
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            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sea Surface Temperature;
Abbreviation: SST_C;
Unit: degrees celcius;
Observation type: Surface Underway;
Analyzing instrument: SBE38;
Uncertainty: Accuracy 0.002 C;
Researcher name: Claire Lo Monaco;
Researcher institution: Univ P et M Curie, France</gco:CharacterString>
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          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Sea Surface Salinity;
Abbreviation: SSS;
Observation type: Surface Underway;
Analyzing instrument: SBE45;
Detailed sampling and analyzing information: Salinometer Guildline AUTOSAL and IAPSO standard / OSI) and to surface CTD data during the casts (SBE04 pre and post-cruise calibrated, IPEV);
Uncertainty: Accuracy 0.01;
Researcher name: Claire Lo Monaco;
Researcher institution: Univ P et M Curie, France</gco:CharacterString>
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          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Barometreic pressure transducer;
Abbreviation: AtmPrs;
Unit: hPa;
Observation type: Surface Underway;
Analyzing instrument: Paroscientific, 1000-16B;
Uncertainty: accuracy 0.08 hPa;
Researcher name: Claire Lo Monaco;
Researcher institution: Univ P et M Curie, France</gco:CharacterString>
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          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Ship speed;
Abbreviation: Ship speed;
Unit: knots;
Observation type: Underway</gco:CharacterString>
              </gmd:description>
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          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Ship Direction;
Abbreviation: Ship Head;
Unit: Degrees;
Observation type: Underway</gco:CharacterString>
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  <gmd:metadataMaintenance>
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        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
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        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
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      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
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        </gmd:CI_ResponsibleParty>
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        <gmi:MI_Instrument id="inst_be58">
          <gmi:identifier>
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              <gmd:code>
                <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
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          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>carbon dioxide (CO2) gas analyzer</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>measures gaseous carbon dioxide

Carbon dioxide gas analyzer has often been referred to as LI-COR, because a lot of researchers choose to use products manufactured by LI-COR incorporation for their carbon dioxide measurement. The main component of a carbon dioxide analyzer is a nondispersive infrared (NDIR) spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption.

Carbon dioxide (CO2) gas analyzer works together with carbon dioxide (CO2) equilibrator (insttypes_id 184) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be57">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>showerhead equilibrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>extracts dissolved CO2 from water

A carbon dioxide equilibrator is usually in the shape of a vertical tube, with a showerhead on the top, some headspace, a lot of beads to increase the surface exchange area between water and air, a water seal device at the bottom to allow water to overflow, but prevents air exchange between inside and outside.

Carbon dioxide (CO2) equilibrator works together with carbon dioxide (CO2) gas analyzer (insttypes_id 183) to measure carbon dioxide in the water.

To measure water carbon dioxide, water needs to be continuously supplied to a showerhead inside an equilibrator. As the water flows through the equilibrator chamber, dissolved carbon dioxide exchanges quickly with air in the headspace. This air is then sampled by the carbon dioxide analyzer to determine the mole fraction of CO2 in water.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:platform>
        <gmi:MI_Platform id="plat_95e4">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>Marion Dufresne</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:description>
            <gco:CharacterString>Built 1995; owned by the French Polar Institute; IMO9050814;

USE NODC CODE 35M1 for all data attributed to vessel MARION DUFRESNE, call sign = FNGB received after December 2009.

NODC CODE 35M1 supercedes NODC code 35MF for French vessel MARION DUFRESNE, call sign = FNGB, which was commissioned in 1973, decommissioned in 1995, renamed FRES in 1995, and destroyed in 2004.</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
      </gmi:platform>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>