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        <gmd:MD_Keywords>
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            <gmx:Anchor xlink:href="https://www.ncei.noaa.gov/archive/archive-management-system/OAS/bin/prd/jquery/seaname/details/107" xlink:actuate="onRequest">South Pacific Ocean</gmx:Anchor>
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                <gco:CharacterString>WMO_CategoryCode</gco:CharacterString>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/4fde380a-38c5-4d46-bc80-4f2515a43983" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; NITRATE</gmx:Anchor>
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          <gmd:keyword>
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          <gmd:keyword>
            <gmx:Anchor xlink:href="https://cmr.earthdata.nasa.gov/kms/concept/4433600b-f323-458a-b295-352f939aab6b" xlink:actuate="onRequest">EARTH SCIENCE &gt; OCEANS &gt; OCEAN CHEMISTRY &gt; PH</gmx:Anchor>
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          <gmd:keyword>
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                <gco:CharacterString>OCADS Study Type</gco:CharacterString>
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            <gmd:MD_KeywordTypeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_KeywordTypeCode" codeListValue="instrument">instrument</gmd:MD_KeywordTypeCode>
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    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:dataQualityInfo>
    <gmd:DQ_DataQuality>
      <gmd:scope>
        <gmd:DQ_Scope>
          <gmd:level>
            <gmd:MD_ScopeCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="dataset">dataset</gmd:MD_ScopeCode>
          </gmd:level>
        </gmd:DQ_Scope>
      </gmd:scope>
      <gmd:lineage>
        <gmd:LI_Lineage>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Dissolved Inorganic Carbon;
Abbreviation: DIC;
Observation type: discrete;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Calculated;
Replicate information: A control chart was prepared using the duplicate data as described in SOP 22 of the DOE handbook (Figure 4). The average non-absolute difference (2nd - 1st in the order of analysis) was 0.38 μmol kg-1 and the standard deviation was 1.2 μmol kg-1. The average value is statistically distinguishable from zero, where zero is the ideal result that would indicate all sources of error were random or independent of both time and the amount of carbon titrated within a given cell. It is thought that this error is related to the chemical evolution of the cell solutions with repeated titrations. However, since the exact nature of these cells’ chemistry is not well-understood, no correction was made to account for this observation.;
Standardization description: A total of 2,935 CT analyses were made including: 1. 189 measurements of Certified Reference Materials (CRM Batch 71, CT 2032.85 ± 0.40 μmol kg-1). 2. 196 sets of duplicate measurements made on separate seawater samples collected from the same Niskin. 3. 86 measurements made on four separate batches of a reference material that were prepared at sea. 4. 25 rejected measurements of samples with known errors. 5. 2439 measurements of sample CT that are presented with quality control codes.;
CRM batch number: 71</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: Total alkalinity;
Abbreviation: TA;
Observation type: discrete;
In-situ / Manipulation / Response variable: in-situ observation;
Measured or calculated: Measured;
Type of titration: potentiometric titration;
Cell type (open or closed): Open;
Curve fitting method: Potentiometric, open-cell titration by coulometrically analyzed hydrochloric acid.;
Uncertainty: The mean and standard deviation for all CRM analyses are 2056.3 ± 3.0 μmol/kg;
Method reference: Dickson, A. G., Afghan, J.D., Anderson, G.C., 2003. Reference Materials for Oceanic CO2 analysis: a Method for the Certification of Total Alkalinity. Marine Chemistry 80, 185-197</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CTDTMP;
Abbreviation: CTDTMP;
Unit: DEG_C;
Controlled vocabulary name: WATER TEMPERATURE;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CTDOXY;
Abbreviation: CTDOXY;
Unit: UMOL/KG;
Controlled vocabulary name: DISSOLVED OXYGEN;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CTDSAL;
Abbreviation: CTDSAL;
Controlled vocabulary name: SALINITY;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: OXYGEN;
Abbreviation: OXYGEN;
Unit: UMOL/KG;
Controlled vocabulary name: DISSOLVED OXYGEN;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: SILCAT;
Abbreviation: SILCAT;
Unit: UMOL/KG;
Controlled vocabulary name: silicate;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: NITRAT;
Abbreviation: NITRAT;
Unit: UMOL/KG;
Controlled vocabulary name: NITRATE;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: NITRIT;
Abbreviation: NITRIT;
Unit: UMOL/KG;
Controlled vocabulary name: NITRITE;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: PHSPHT;
Abbreviation: PHSPHT;
Unit: UMOL/KG;
Controlled vocabulary name: phosphate;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CFC-11;
Abbreviation: CFC-11;
Unit: PMOL/KG;
Controlled vocabulary name: CHLOROFLUOROCARBON-11 (CFC-11);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CFC-12;
Abbreviation: CFC-12;
Unit: PMOL/KG;
Controlled vocabulary name: CHLOROFLUOROCARBON-12 (CFC-12);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CFC113;
Abbreviation: CFC113;
Unit: PMOL/KG;
Controlled vocabulary name: CHLOROFLUOROCARBON-113 (CFC-113);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: CCL4;
Abbreviation: CCL4;
Unit: PMOL/KG;
Controlled vocabulary name: Carbon tetrachloride (CCL4);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: TCARBN;
Abbreviation: TCARBN;
Unit: UMOL/KG;
Controlled vocabulary name: DISSOLVED INORGANIC CARBON (DIC);
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>Parameter or Variable: ALKALI;
Abbreviation: ALKALI;
Unit: UMOL/KG;
Controlled vocabulary name: total alkalinity;
In-situ / Manipulation / Response variable: in-situ observation</gco:CharacterString>
              </gmd:description>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:dataQualityInfo>
    <gmd:DQ_DataQuality>
      <gmd:scope>
        <gmd:DQ_Scope>
          <gmd:level>
            <gmd:MD_ScopeCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_ScopeCode" codeListValue="repository">repository</gmd:MD_ScopeCode>
          </gmd:level>
          <gmd:levelDescription>
            <gmd:MD_ScopeDescription>
              <gmd:other>
                <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
              </gmd:other>
            </gmd:MD_ScopeDescription>
          </gmd:levelDescription>
        </gmd:DQ_Scope>
      </gmd:scope>
      <gmd:lineage>
        <gmd:LI_Lineage>
          <gmd:processStep>
            <gmi:LE_ProcessStep>
              <gmd:description>
                <gco:CharacterString>NOAA created the National Centers for Environmental Information (NCEI) by merging NOAA's National Climatic Data Center (NCDC), National Geophysical Data Center (NGDC), and National Oceanographic Data Center (NODC), including the National Coastal Data Development Center (NCDDC), per the Consolidated and Further Continuing Appropriations Act, 2015, Public Law 113-235. NCEI launched publicly on April 22, 2015.</gco:CharacterString>
              </gmd:description>
              <gmd:dateTime>
                <gco:DateTime>2015-04-22T00:00:00</gco:DateTime>
              </gmd:dateTime>
            </gmi:LE_ProcessStep>
          </gmd:processStep>
        </gmd:LI_Lineage>
      </gmd:lineage>
    </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
      <gmd:maintenanceNote>
        <gco:CharacterString>Metadata are developed, maintained and distributed by NCEI. Updates are performed as needed to maintain currentness.</gco:CharacterString>
      </gmd:maintenanceNote>
      <gmd:contact>
        <gmd:CI_ResponsibleParty>
          <gmd:organisationName>
            <gco:CharacterString>NOAA National Centers for Environmental Information</gco:CharacterString>
          </gmd:organisationName>
          <gmd:role>
            <gmd:CI_RoleCode codeList="https://data.noaa.gov/resources/iso19139/schema/resources/Codelist/gmxCodelists.xml#CI_RoleCode" codeListValue="custodian">custodian</gmd:CI_RoleCode>
          </gmd:role>
        </gmd:CI_ResponsibleParty>
      </gmd:contact>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
  <gmi:acquisitionInformation>
    <gmi:MI_AcquisitionInformation id="AMS">
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_beec">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>bottle</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>bottle</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>any type of water bottle sampling device

Generic name for water collection device; usually used to determine temperature, salinity and provide water aliquots for measurement of a wide range of parameters; often referred to by a specific type of water sampling bottle, such as a Nansen or Niskin bottle.</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be29">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>coulometer for DIC measurement</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>coulometer for DIC measurement</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>measures dissolved inorganic carbon (DIC)

A known amount of seawater is dispensed into a stripping chamber where it is acidified and purged with an inert gas. The amount of CO2 in the resulting gas stream is determined by absorbing the CO2 in an absorbent. The pH of the solution is monitored by measuring the transmittance .</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_bee7">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>CTD</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>CTD</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>Conductivity-Temperature-Depth probe</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:instrument>
        <gmi:MI_Instrument id="inst_be28">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>titrator</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:type>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:type>
          <gmi:description>
            <gco:CharacterString>titrator</gco:CharacterString>
          </gmi:description>
        </gmi:MI_Instrument>
      </gmi:instrument>
      <gmi:platform>
        <gmi:MI_Platform id="plat_b71b">
          <gmi:identifier>
            <gmd:MD_Identifier>
              <gmd:code>
                <gco:CharacterString>R/V Knorr</gco:CharacterString>
              </gmd:code>
            </gmd:MD_Identifier>
          </gmi:identifier>
          <gmi:description>
            <gco:CharacterString>Title: R/V
Flag: United States of America
Vessel Type: Research Vessel (Oceanographic)
DOB: 1970
IMO: 7738618
MMSI: 367246000</gco:CharacterString>
          </gmi:description>
          <gmi:instrument gco:nilReason="missing" />
        </gmi:MI_Platform>
      </gmi:platform>
    </gmi:MI_AcquisitionInformation>
  </gmi:acquisitionInformation>
</gmi:MI_Metadata>